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301.
Many methods have been proposed to model joints in rocks or the interface between soil and a structure. Many analysts have reported numerical problems when using zero thickness interface elements while others have presented satisfactory results without comment of such difficulties. The numerical behaviour of zero thickness interface elements is further investigated in this paper. Some simple examples illustrate the application of interface elements to practical situations and highlight the numerical difficulties that may be encountered. Both ill-conditioning of the stiffness matrix and high stress gradients were found to cause numerical instability. Ill-conditioning can be reduced by careful selection of the size of the 2D elements adjacent to the interface. The problem of steep stress gradients is entirely one of inadequate mesh design. Contrary to other reports, this paper shows that the Newton–Cotes integration scheme has no benefit over Gaussian integration. Analyses of a retaining wall using interface elements confirm the analytical values of active and passive earth pressure coefficients which are commonly used in analysis and design of retaining walls.  相似文献   
302.
The complex dark brown solid of a class called tholins, produced on passage of an electrical discharge through a roughly equimolar mixture of methane and ammonia with 2.6% water vapor, is analyzed by vacuum pyrolysis followed by gas chromatography and mass spectrometry. Pyrolyzates include a wide range of aliphatic and aromatic nitriles, alkanes, aromatic hydrocarbons, pyrrole, and pyridine. This tholin is remarkably stable to 950°C. It and its degradation products are candidate constituents of planetary aerosols in the outer solar system and of the grains in the interstellar medium.  相似文献   
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Many granitic bodies intrude the basement gneisses in Meghalaya Plateau, Northeast India. Rb-Sr whole-rock isotopic ages of the granitoids range from 881 to 479 Ma while the ages of the basement orthogneisses vary from 1714 to 1150 Ma. All the plutons are dominantly metaluminous and show geochemical variation. Oxygen isotopic compositions in the granitoids and gneisses are concordant (d18O: + 5.78% to + 8.70%). However, the gneisses from high-grade terrain have low d18O value of +2.52% to +5.31%. Initial 87Sr/86Sr (ISr) ratios of the plutons vary from 0.70459 to 0.71487 and tend to increase with progressive younging in age. The geochemical characters suggest derivation of the granites from lower crustal source. The fractionated rare earth patterns observed in the granitoids can be obtained by partial melting of gneisses or diorites. Some gneiss samples have experienced interaction with hydrothermal fluids resulting in lowering d18O. The isotopic ages of granite plutonism in Meghalaya are similar to the plutonic and tectonothermal events in other parts of India, southwestern Australia and document final amalgamation events of the Gondwana Supercontinent.  相似文献   
305.
The Lost City Hydrothermal Field at 30°N, near the Mid-Atlantic Ridge, is an off-axis, moderate temperature, high-pH (9-10.8), serpentinite-hosted vent system. The field is hosted on ∼1.5 Ma crust, near the summit of the Atlantis Massif. Within the field, actively venting carbonate chimneys tower up to 60 m above the seafloor, making them the tallest vent structures known. The chemistry of the chimneys and vent fluids is controlled by serpentinization reactions between seawater and underlying peridotite. Mixing of <40-91 °C calcium-rich vent fluids with seawater results in the precipitation of variable mixtures of aragonite, calcite, and brucite. The resultant deposits range from tall, graceful pinnacles to fragile flanges and delicate precipitates that grow outward from fissures in the bedrock. In this study, mineralogy, petrographic analyses, major and trace element concentrations, and Sr isotopic compositions are used to propose a model for the growth and chemical evolution of carbonate chimneys in a serpentinite-hosted environment. Our results show that nascent chimneys are characterized by a porous, interlacing network of aragonite, and brucite minerals that form extremely fragile structures. The chemistry of these young deposits is characterized by ∼10 wt% Ca and up to 27 wt% Mg, extremely low trace metal concentrations, and 87Sr/86Sr isotope ratios near 0.70760. During aging of the chimneys, progressive reactions with seawater result in the dissolution of brucite, the conversion of aragonite to calcite, and infilling of pore spaces with calcite. The oldest chimneys are dominated by calcite, with bulk rock values of up to 36 wt% Ca and <1 wt% Mg. These older structures contain higher concentrations of trace metals (e.g., Mn and Ti), and have Sr isotope ratios near seawater values (0.70908). Exposed ultramafic rocks are prevalent along the Mid-Atlantic, Arctic, and Indian Ocean ridge networks and it is likely that other Lost City-type systems exist.  相似文献   
306.
Ombrogenic Atlantic salt marshes are defined as areas of halophytic, terrestrial vegetation which are periodically flooded by the tide and have a predominant underlying organic substrate comprising of wood and/or Sphagnum peat that formed under freshwater conditions. The objective of this study was to determine to what extent salt marsh plant ecology and, specifically, vegetation composition and zonation relate to this underlying substrate of organic matter (peat). A vegetation survey was carried out on nine salt marshes, three on peat substrate and two on sand, mud and sand/mud, respectively. In parallel, key edaphic variables were measured including pH, conductivity, organic content, moisture content and nutrients: ammonium, nitrate and phosphorus. Salt marshes on peat substrate are distinct. Ammonium content was twice the maximum reported in other salt marsh studies, while the vegetation composition of salt marshes on peat substrate was significantly different from that of other salt marshes. Salt marshes on peat substrate were found to be higher in species diversity and richness and characterised by a predominantly forb and rush community. However, some common salt marsh species, such as Atriplex portulacoides and Spartina anglica were absent from salt marshes on peat. Ordination analysis revealed that zonation was primarily associated with conductivity on peat substrates. In contrast, moisture plays a greater role in zonation within non-peat salt marshes. The findings confirm that the high organic matter content of ombrogenic Atlantic salt marshes is associated with distinct vegetation composition.  相似文献   
307.
Three anthropogenic sources (urban, soil, and industrial runoff) were characterized for bulk nutrient and dissolved organic matter (DOM) composition using wet chemistry and Fourier transform ion cyclotron resonance mass spectrometry. Each source was unique based on its chemical composition. Dissolved inorganic nitrogen (N) comprised 91, 60, and 20 % of the total N pool in the soil, urban, and industrial sources, respectively. The DOM composition was dominated by terrestrial compounds in the soil, condensed hydrocarbons, lipids and proteins in the urban, and lipid-like compounds in the industrial source. A York River (VA) phytoplankton assemblage, dominated by Cochlodinium polykrikoides, was amended with the sources during a 7-day bioassay. There was a doubling of chlorophyll a and/or cell concentrations within 2 days, in the +Urban and +Soil treatments. The + Industrial treatment supported algal growth, but increases in cell abundances were only statistically significant at the end of the experiment (days 5–7), suggesting that this material was less labile to the original York River community than the other anthropogenic nutrient sources, on the relatively short timescale of the study.  相似文献   
308.
309.
The purpose of this research is to investigate what factors influence the management of International Business Air Travel (IBAT). The researchers interviewed 34 business travellers, travel organisers and executives involved in IBAT from ten organisations in differing industries, in Australia. It was found that there are a multitude of factors influencing IBAT management, including professionalism and job satisfaction of travellers and the achievement of organisational goals such as carrying out successful international ventures or operating effectively in international markets. From the findings a strategic model was developed called the Threshold of Tolerance Model—which illustrates the potential point where both organisational goals are most likely to be met and where IBAT is most likely to be well managed for both travellers and organisations.  相似文献   
310.
Presented here are analyses of the photometric measurements acquired by the imaging system on the MESSENGER spacecraft during its three flybys of Mercury, in particular the dedicated sequence of photometric measurements obtained during the third flyby. A concise, analytical approach is adopted for characterizing the effects of scattered light on the images. This approach works well for wavelengths shorter than 700 nm but breaks down at the longer wavelengths where the scattering behavior of the imaging system is more complex. Broadband spectral properties are commensurate with ground-based observations for spectra acquired at phase angles less than 110°; photometric corrections to a common illumination and viewing geometry provide consistent results for those phase angles. No phase reddening is apparent in the image-derived spectra. A bolometric albedo of 0.081 is derived over the wavelength range of the imaging system.  相似文献   
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